A sodium-ion battery is a rechargeable battery that uses sodium ions as the charge carrier. Like lithium-ion and lead-acid batteries, it belongs to the “rocking chair” battery system.
Its core working principle is: using an organic electrolyte as a carrier, sodium ions repeatedly insert and extract between the positive and negative electrodes to complete the charging and discharging process.
Sodium ions are extracted from the positive electrode material, pass through the electrolyte, and insert into the negative electrode material. Electrons simultaneously flow to the negative electrode through the external circuit, converting electrical energy into chemical energy for storage.
Sodium ions are extracted from the negative electrode material, pass through the electrolyte, and insert into the positive electrode material. Electrons simultaneously flow to the positive electrode through the external current, converting chemical energy back into electrical energy to supply power.
Positive electrode materials: Sodium-ion battery positive electrode materials are abundant and inexpensive. Although their energy density is relatively low, they have strong structural stability, good safety, and long cycle life.
Negative electrode materials: Hard carbon, as a sodium-ion battery negative electrode material, has a larger structural porosity, making it suitable for sodium-ion battery insertion and extraction. It is derived from a wide range of biological materials, such as bamboo, reeds, coconut shells, and nut shells, making it sustainable.
Electrolyte: Sodium hexafluorophosphate, as a sodium-ion battery electrolyte, shares production equipment and production lines with lithium-ion battery electrolytes (lithium hexafluorophosphate), making it easier to scale up production and lower in cost.
| Battery Technology | Cathode | Anode | Eelectrolyte |
| Lead-acid Battery(Lead Acid ) | lead-antimony-calcium alloy plate;lead oxide as the active substance | Lead – antimony – calcium alloy plate;Spongy fiber active material | Sulfuric Acid |
| Sodium-ion Battery (Polyanionic ) | Sodium ferric phosphate;Sodium ferric sulfate | Hard Carbon | Sodium Hexafluorophoshate |
Comparing sodium-ion batteries and lead-acid batteries, 90% of the materials in lead-acid batteries are derived from lead. Lead-acid batteries contain toxic elements such as antimony and barium, and sulfuric acid, as the electrolyte, is corrosive. Therefore, lead-acid batteries are not only polluting but also toxic.
Starting in 2026, from the perspective of the development of China’s mainstream sodium-ion battery industry, NFPP sodium-ion batteries (NFPP Sodium Ion Battery) have become the mainstream sodium-ion battery technology, because of their advantages such as long cycle life, low material cost, and ability to pass the nail penetration test, and are widely used in energy storage scenarios.
The core materials of NFPP sodium-ion battery are: positive electrode materials (sodium iron phosphate and sodium iron sulfate), negative electrode materials (hard carbon), and electrolyte (sodium hexafluorophosphate).
| Items | Lead Acid Battery | Sodium Ion Battery |
| Energy density(wh/kg) | 30-50 | 90~110 |
| Voltage range(V) | 1.5~2.4 | 1.5~3.6 |
| Rated voltage(V) | 2 | 2.85 |
| Cycle life @25℃, 80%DOD | 300-500 | 8000-10000 |
| Charge rate(C) | 0.2 | 1 |
| Operation temperature(℃) | 20-25 | -40-80 |
| Self-discharge rate | 3%-5% | 0.3%-0.5% |
| Warranty Life(Years) | 3 | 7 |
In comparison, lead-acid batteries have extremely low energy density, a very short cycle life, low charging efficiency leading to long charging times, particularly poor high- and low-temperature performance, and a very high self-discharge rate, failing to meet the needs of energy storage users.
| Battery Technology | Cathode | Anode | Eelectrolyte |
| Li-ion Battery (LFP) | Lithium iron phosphate *Aluminum | Graphite*Copper | Lithium hexafluorophosphate |
| Li-ion Battery (NMC) | Cobalt Lithium Manganese Nickel oxide *Iron;*Aluminum;*Silicon | Graphite*Copper | Lithium hexafluorophosphate |
| Sodium-ion Battery(NFPP) | Sodium ferric phosphate Sodium ferric sulfate | Hard Carbon | Sodium Hexafluorophoshate |
By comparing sodium-ion batteries and lithium-ion batteries, lithium-ion batteries mainly rely on the material lithium (lithium carbonate). In addition, ternary lithium-ion batteries also contain materials such as cobalt and nickel. Lithium-ion battery materials have many problems, such as safety hazards and short cycle life. They cannot fundamentally suppress the growth of lithium dendrites, which can easily puncture the separator, causing short circuits and ultimately leading to thermal runaway.
| Items | LFP | SIB |
| Energy density(wh/kg) | 150~180 | 90~110 |
| Voltage range(V) | 2.65~3.6 | 1.5~3.6 |
| Rated voltage(V) | 3.2 | 2.85 |
| Capacity retention rate @-20℃ | 55% | 94% |
| Capacity retention rate @-40℃ | 0% | 85% |
| Cycle life @25℃, 80%DOD | 6000-8000 | 8000-10000 |
In comparison, sodium-ion batteries are safer, have a longer cycle life, a wider operating temperature range, higher charge and discharge rates, and higher charging and discharging efficiency. Their material system is also more environmentally friendly. However, currently, sodium-ion batteries have a lower energy density and higher cost per watt-hour than lithium-ion batteries. The choice between sodium-ion and lithium-ion batteries depends on the specific energy storage application scenario and requires evaluation and analysis.
| Safety Items | LFP | NFPP SIB |
| Initiation temperature of Thermal runaway | 160℃-200℃ | Over 500℃ |
| Risk of thermal runaway | It is prone to generating oxygen and releasing heat under extreme conditions, posing a risk of fire and explosion. | positive electrode releases low oxygen, and the stable hard carbon negative electrode completely blocks heat diffusion. |
| Charging safety in low-temperature | It is prone to lithium plating when charged below 0°C. Dendrite accumulation can lead to short circuits, and low-temperature charging poses significant safety risks. | Charging at -20℃ remains safe; dendrite growth will not cause the diaphragm to puncture and thus lead to a short circuit. |
| Structural safety | LFP batteries must use copper foil as the negative electrode. Over-discharge can easily cause the copper foil to dissolve, leading to the risk of internal short circuits. | Aluminum foil can be used as the negative electrode current collector. Aluminum and sodium do not form an alloy, so even in the event of over-discharge, there will be no corrosion or dissolution of the current collector. |
Advantage 4: Polyanion sodium-ion batteries have a longer cycle life. They offer better cycle life and capacity efficiency (low capacity decay rate even at 45°C high-temperature cycling); there is almost no temperature rise during charging and low temperature rise during discharging, making them easier to manage in large modules.
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